The Electrochemistry of the Methylhydrazines
نویسنده
چکیده
The electrooxidation of methylhydrazine, 1,2-dirnethylhydrazine, and 1,1 -dimethylhydrazine at a platinum electrode was studied using chronopotentiometry, coulometry, and product analysis. The results show that methjJlhydrazine is oxidized in an over-all four-electron reaction to nitrogen and methanol. The oxidation of 1,2-dimethylhydvazine proceeds by an initial two-electron oxidation, followed by a chemical reaction leading to formation of formaldehyde and methylhydrazine. The oxidation of 1,l-dimethylhydrazine occurs b y a two-electron oxidation to 1,l-dimethyldiazene which undergoes a relatively slow chemical decomposition.
منابع مشابه
Electron spin resonance studies of cation radicals produced during oxidation of methylhydrazines
The Journal of Physical Chemistry is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Electron spin resonance studies of cation radicals produced during oxidation of methylhydrazines Allen J. Bard, and Thomas V. Atkinson J. Phys. Chem., 1971, 75 (13), 2043-2048• DOI: 10.1021/j100682a023 • Publication Date (Web): 01 May 2002 Downloaded from http://pubs...
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